CAS:934047-83-3 | 1,3-Bis(cyanomethyl)imidazolium Chloride

Introduction of CAS:934047-83-3 | 1,3-Bis(cyanomethyl)imidazolium chloride

1,3-bis(cyanomethyl)-1H-imidazol-3-ium chloride, also known as Dicyclohexylcarbodiimide (DCC), is a widely used chemical reagent in organic synthesis. It is a white crystalline solid that is soluble in polar solvents such as water, ethanol, and acetone. DCC is commonly used to activate carboxylic acids for peptide synthesis, as well as for the synthesis of esters, amides, and other organic compounds.

Specification of CAS:934047-83-3 | 1,3-Bis(cyanomethyl)imidazolium chloride

Research Application of CAS:934047-83-3 | 1,3-Bis(cyanomethyl)imidazolium chloride

 Related Metal N-Heterocyclic Carbene Complexes: This study focuses on the synthesis of hydrophilic N-heterocyclic carbene (NHC) ligand precursors related to 1,3-bis(cyanomethyl)-1H-imidazol-3-ium chloride. These precursors are used to synthesize carbene complexes of silver(I), copper(I), and gold(I), which demonstrate cytotoxic properties against various human cancer cell lines, including cisplatin-sensitive and -resistant cells. The silver(I) complex was notably active, and the gold(I) and silver(I) carbene complexes also showed potential to inhibit the enzyme thioredoxin reductase (TrxR) at nanomolar concentrations (Pellei et al., 2012).

Elusive Free Bisimino-N-heterocyclic Carbene and Its Rearrangement by C–C Coupling: This research presents the synthesis of a potentially pincer-type N-heterocyclic carbene precursor salt. The study explores the structural and spectroscopic properties of these compounds and their reactions with iridium(I) and chromium(II) complexes (Liu et al., 2013).

A Bottleable Imidazole-Based Radical as a Single Electron Transfer Reagent: This study reports the formation of the first structurally characterized imidazole-based radical, which was established as a single electron transfer reagent. This radical was used in various organic transformations, such as activation of an aryl-halide bond and catalytic reduction of CO2 to methoxyborane under ambient conditions (Das et al., 2020).

Synthesis and Fluorescence Properties of α,α′-Bis(substituted-benzylidene)cycloalkanones Catalyzed by 1-Methyl-3(2-(sulfooxy)ethyl)-1H-imidazol-3-ium Chloride: This paper explores the synthesis of α,α′-Bis(substituted-benzylidene)cycloalkanones via a solvent-free cross-aldol condensation catalyzed by a derivative of 1,3-bis(cyanomethyl)-1H-imidazol-3-ium chloride. The study also investigates the influence of the size of cycloalkanone on the fluorescence emission of the products (Wan et al., 2010).

Electrochemical Reduction of an Imidazolium Cation: This research describes the electrochemical and chemical reduction of 1,3-bis(2,4,6-trimethylphenyl)imidazolium chloride to produce a nucleophilic carbene. The carbene was shown to be compatible with and persistent in the ionic liquid tetradecyl(trihexyl)phosphonium chloride (Gorodetsky et al., 2004).

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