CAS:80655-81-8 | (S)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol

Introduction of CAS:80655-81-8 | (S)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol

(-)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol, also known as DBN, is a brominated naphthol compound that has been widely used in organic synthesis and scientific research. DBN is a powerful reagent that can be used to synthesize a variety of compounds, including pharmaceuticals, dyes, and other organic molecules. It is also used in biochemical and physiological research, as it can be used to study the effects of various compounds on living organisms.

Specification of CAS:80655-81-8 | (S)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol

Related Articles of CAS:80655-81-8 | (S)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol

Chiral Catalysts for Asymmetric Synthesis

(R)-6,6'-Dibromo-1,1'-bi-2-naphthol has been used in the preparation of novel chiral catalysts, particularly in enantioselective Mannich-type reactions. These reactions are significant in the synthesis of optically active β-amino acid derivatives, showcasing the importance of chiral catalysts in asymmetric synthesis (Ishitani et al., 2000).

Polymeric Applications

6,6'-Dibromo-1,1'-bi-2-naphthol derivatives have been used in the synthesis of polymers, specifically poly(1,1'-bi-2-naphthol)s [poly(BINOL)s]. These polymers have applications in Lewis acid catalysis, where they have been used to create polymeric Lewis acid complexes, representing a new generation of polymeric catalysts. These catalysts have been utilized in the Mukaiyama aldol condensation, demonstrating enhanced catalytic efficiency due to the organized catalytic centers within the optically active and regular polymer chain (Hu et al., 1996).

Chiral Polyurethane Synthesis

(R)-1,1'-Bi(2-naphthol) has been instrumental in the synthesis of chiral polyurethane, leading to polymers with a π-stacked, 2/1-helical conformation. This conformation is significant in the field of polymer chemistry, particularly in understanding the stability and dynamics of polymer chains in different temperature ranges (Gudeangadi et al., 2015).

Crystal Engineering

(R)-(+)-1,1'-Bi-2-naphthol has been used in crystal engineering to construct chiral organo-organometallic crystals. These crystals have potential applications in the study of molecular aggregation and interactions in crystalline structures, highlighting the role of chiral building blocks in crystal engineering (Grepioni et al., 2001).

Chiroptical Spectroscopic Methods

The compound has been the subject of study in chiroptical spectroscopic methods, particularly in understanding the conformational sensitivity of different spectroscopic techniques. These studies provide insights into the structural and conformational aspects of chiral molecules, which are crucial in the field of stereochemistry (Polavarapu et al., 2009).

Hot Tags: cas:80655-81-8 | (s)-(-)-6,6'-dibromo-1,1'-bi-2-naphthol, China cas:80655-81-8 | (s)-(-)-6,6'-dibromo-1,1'-bi-2-naphthol manufacturers, factory, Chemical Reagents, Methyltin mercaptide