Introduction of CAS:131818-17-2 | TERT-BUTYL N-(4-BROMOPHENYL)-CARBAMATE
Tert-Butyl (4-bromophenyl)carbamate (TBC) is an organic compound that has been used in a variety of scientific experiments and research applications. TBC is a relatively new compound, first synthesized in the early 2000s, and has since been used in a variety of studies due to its unique characteristics.
Specification of CAS:131818-17-2 | TERT-BUTYL N-(4-BROMOPHENYL)-CARBAMATE
|
ITEMS |
SPECIFICATION |
|
Melt point |
103-106 °C(lit.) |
|
Acidity coefficient (pKa) |
12.99±0.70(Predicted) |
|
Boiling point |
281.1±23.0 °C(Predicted) |
|
Density |
1.398 |
|
From |
Powder |
|
Color |
White |
|
Storage condition |
2-8°C |
Related Articles of CAS:131818-17-2 | TERT-BUTYL N-(4-BROMOPHENYL)-CARBAMATE
1. Use in Safety-Catch Nitrogen Protecting Group
The 9-(4-bromophenyl)-9-fluorenyl (BrPhF) group, a novel safety-catch amine protection, can be activated by palladium-catalyzed cross-coupling reaction of the aryl bromide with morpholine and then cleaved effectively under mild conditions. This group has complementary conditions for selective removal in the presence of tert-butyl esters and carbamates (Surprenant & Lubell, 2006).
2. As a Silylating Agent
Trimethylsilyl N-(4-bromophenyl)carbamate is an important silylating agent, with structures dominated by a plane containing a large number of atoms, organized by delocalization around the carbamate moiety (Böcskei et al., 1996).
3. In Organic Photovoltaic Materials
Tert-Butyl bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate is synthesized via hydrolysis of its tert-butyl carbamate derivative for use in organic photovoltaic materials (Chmovzh & Rakitin, 2021).
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