Introduction and application of CAS 94041-18-6 | (S)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenyl-1,1'-phosphine oxide]
(S)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenyl-1,1'-phosphine oxide] is a diphosphine ligand that has been used to catalyze the amination reaction of β-amino acids with aromatic hydrocarbons. The phosphine oxide moiety of this compound reacts with the aromatic hydrocarbon and the resulting intermediate can react with β-amino acid to form an amide.
This reaction is chiral and yields a homogeneous assay. The phosphine oxide moiety also has functional groups that can react with acidic catalysts such as HCl or HBr to produce an amide.
Synonyms:
(R)-2,2'-bis(diphenylphosphoryl)-1,1'-binaphthyl;
(S)-[1,1'-Binaphthalene]-2,2'-diyl bis[1,1-diphenyl-1,1'-phosphine oxide];
Specification of CAS 94041-18-6 | (S)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenyl-1,1'-phosphine oxide]
|
ITEMS |
SPECIFICATION |
|
CAS |
94041-18-6 |
|
MF |
C44H32O2P2 |
|
MW |
654.67 |
|
Boiling point |
864.8±65.0 °C(Predicted) |
|
Density |
1.30±0.1 g/cm3(Predicted) |
Package and transportation of Introduction and application of CAS 94041-18-6 | (S)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenyl-1,1'-phosphine oxide]
Package:0.1g,1g,5g,25g,100g,500g,1kg
Transportation: by courier/ by air/ by sea


Related Articles of CAS 94041-18-6 | (S)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenyl-1,1'-phosphine oxide]
Catalyst-Tuned Electrophilic Chlorination of Diverse Aromatic Compounds with Sulfuryl Chloride and Regioselective Chlorination of Phenols with Organocatalysts
E Erturk, TA Yeşil - The Journal of Organic Chemistry, 2022 - ACS Publications
… phosphine sulfide [(S)-[1,1′-binaphthalene]-2,2′-diylbis(1,1-diphenyl-1,1′-phosphine
sulfide)] … , we thought that this would be useful for the chlorination of oxidation-labile aromatic …
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